| Literature DB >> 18345628 |
Andrea Sartorel1, Mauro Carraro, Gianfranco Scorrano, Rita De Zorzi, Silvano Geremia, Neal D McDaniel, Stefan Bernhard, Marcella Bonchio.
Abstract
Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.Entities:
Year: 2008 PMID: 18345628 DOI: 10.1021/ja077837f
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419