Literature DB >> 18338041

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes.

Toshimichi Ohmura1, Kazuyuki Oshima, Michinori Suginome.   

Abstract

Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group.

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Year:  2008        PMID： 18338041     DOI： 10.1039/b800181b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis of Functionalized Hydrazines: Facile Homogeneous (N-Heterocyclic Carbene)-Palladium(0)-Catalyzed Diboration and Silaboration of Azobenzenes.

Authors:  Melvyn B Ansell; George E Kostakis; Holger Braunschweig; Oscar Navarro; John Spencer
Journal:  Adv Synth Catal       Date:  2016-11-09       Impact factor: 5.837

Review 2.  Geometric E→Z Isomerisation of Alkenyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal anti-Metallometallation.

Authors:  Svenja I Faßbender; John J Molloy; Christian Mück-Lichtenfeld; Ryan Gilmour
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-31       Impact factor: 15.336
  2 in total

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