Literature DB >> 18331045

Convenient synthesis of branched-chain glycosamines by radical addition of nitromethane to glycals.

Elangovan Elamparuthi1, Torsten Linker.   

Abstract

Radical addition-reduction-acetylation is the simple three-step sequence for the synthesis of branched-chain glycosamines 3 from glycals 1 and nitromethane (2). The intermediary formed 2-C-nitromethyl-pyranosides are valuable precursors for the synthesis of C-2 branched disaccharides.

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Year:  2008        PMID: 18331045     DOI: 10.1021/ol703062s

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Synthesis and conformational analysis of linear homo- and heterooligomers from novel 2-C-branched sugar amino acids (SAAs).

Authors:  Guang-Zong Tian; Jing Hu; Heng-Xi Zhang; Christoph Rademacher; Xiao-Peng Zou; Hong-Ning Zheng; Fei Xu; Xiao-Li Wang; Torsten Linker; Jian Yin
Journal:  Sci Rep       Date:  2018-04-26       Impact factor: 4.379

  1 in total

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