Literature DB >> 18309421

Fe-Cu cooperative catalysis in the isomerization of alkyl Grignard reagents.

Eiji Shirakawa1, Daiji Ikeda, Shigeru Yamaguchi, Tamio Hayashi.   

Abstract

Alkyl Grignard reagents were found to be isomerized to more stable ones in high isomerization ratios (>99%) under cooperative catalysis by iron and copper, which promote isomerization of alkyl groups and transmetalation between Fe-Mg, respectively.

Entities:  

Year:  2008        PMID: 18309421     DOI: 10.1039/b717717h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Mechanism of the Bis(imino)pyridine-Iron-Catalyzed Hydromagnesiation of Styrene Derivatives.

Authors:  Peter G N Neate; Mark D Greenhalgh; William W Brennessel; Stephen P Thomas; Michael L Neidig
Journal:  J Am Chem Soc       Date:  2019-06-17       Impact factor: 15.419

  1 in total

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