Literature DB >> 18305846

Microwave-promoted insertion of Group 10 metals into free base porphyrins and chlorins: scope and limitations.

Michelle L Dean1, Jason R Schmink, Nicholas E Leadbeater, Christian Brückner.   

Abstract

The scope and limitations of microwave heating as a tool for insertion of Group 10 metals into meso-tetraphenyl-porphyrin, -porpholactone, and -2,3-dihydroxychlorin derivatives are discussed. In some cases it is possible to reduce reaction times dramatically while obtaining good yields of the metallated products while in others new issues arise relating to the metal salt used as well as acceleration not only of the metallation reaction but also of byproduct formation.

Entities:  

Year:  2008        PMID： 18305846     DOI： 10.1039/b716181f

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  6 in total

1.  meso-arylporpholactones and their reduction products.

Authors:  Christian Brückner; Junichi Ogikubo; Jason R McCarthy; Joshua Akhigbe; Michael A Hyland; Pedro Daddario; Jill L Worlinsky; Matthias Zeller; James T Engle; Christopher J Ziegler; Matthew J Ranaghan; Megan N Sandberg; Robert R Birge
Journal:  J Org Chem       Date:  2012-07-19       Impact factor: 4.354

2.  Platinum(II) Ring-Fused Chlorins as Near-Infrared Emitting Oxygen Sensors and Photodynamic Agents.

Authors:  Nelson A M Pereira; Mafalda Laranjo; João Casalta-Lopes; Arménio C Serra; Marta Piñeiro; João Pina; J Sérgio Seixas de Melo; Mathias O Senge; M Filomena Botelho; Liliana Martelo; Hugh D Burrows; Teresa M V D Pinho E Melo
Journal:  ACS Med Chem Lett       Date:  2017-02-22       Impact factor: 4.345

3.  Synthesis and photophysical properties of sulfonamidophenyl porphyrins as models for activatable photosensitizers.

Authors:  Jayeeta Bhaumik; Ralph Weissleder; Jason R McCarthy
Journal:  J Org Chem       Date:  2009-08-21       Impact factor: 4.354

4.  Two-photon oxygen sensing with quantum dot-porphyrin conjugates.

Authors:  Christopher M Lemon; Elizabeth Karnas; Moungi G Bawendi; Daniel G Nocera
Journal:  Inorg Chem       Date:  2013-08-26       Impact factor: 5.165

5.  Synthesis of phosphorescent asymmetrically π-extended porphyrins for two-photon applications.

Authors:  Tatiana V Esipova; Sergei A Vinogradov
Journal:  J Org Chem       Date:  2014-09-05       Impact factor: 4.354

6.  Oxazolochlorins 21. Most Efficient Access to meso-Tetraphenyl- and meso-Tetrakis(pentafluorophenyl)porpholactones, and Their Zinc(II) and Platinum(II) Complexes.

Authors:  Damaris Thuita; Dinusha Damunupola; Christian Brückner
Journal:  Molecules       Date:  2020-09-22       Impact factor: 4.411
  6 in total

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