| Literature DB >> 18303905 |
Eranda Wanigasekara1, Carmine Gaeta, Placido Neri, Dmitry M Rudkevich.
Abstract
Calix[4]monohydroquinone has been used as a supramolecular system for the generation of NO gas. In a one-electron reduction scheme involving NO+ subsetcalix[4]monohydroquinone complex, NO is released without the presence of an external reducing agent. Free calix[4]monoquinone, thus obtained, can be reused for a new NO-releasing cycle after NaBH4-reduction to calix[4]monohydroquinone.Entities:
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Year: 2008 PMID: 18303905 DOI: 10.1021/ol800156m
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005