Literature DB >> 18303899

Intermolecular radical addition of alkylthio- and arylthiodiphenylphosphines to terminal alkynes.

Tatsuya Wada1, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima.   

Abstract

Intermolecular radical thiophosphination of terminal alkynes with alkylthio- and arylthiophosphines affords 1-thio-2-phosphino-1-alkenes in good yields. The addition reaction proceeds predominantly in an anti fashion to yield E isomers.

Entities:  

Year:  2008        PMID： 18303899     DOI： 10.1021/ol800059n

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

Review 1.  Alkynoates as Versatile and Powerful Chemical Tools for the Rapid Assembly of Diverse Heterocycles under Transition-Metal Catalysis: Recent Developments and Challenges.

Authors:  Imtiaz Khan; Aliya Ibrar; Sumera Zaib
Journal:  Top Curr Chem (Cham)       Date:  2021-01-05

2.  Photoinduced Bisphosphination of Alkynes with Phosphorus Interelement Compounds and Its Application to Double-Bond Isomerization.

Authors:  Yuki Yamamoto; Ryo Tanaka; Shintaro Kodama; Akihiro Nomoto; Akiya Ogawa
Journal:  Molecules       Date:  2022-02-14       Impact factor: 4.411

3.  Homolytic substitution at phosphorus for C-P bond formation in organic synthesis.

Authors:  Hideki Yorimitsu
Journal:  Beilstein J Org Chem       Date:  2013-06-28       Impact factor: 2.883
  3 in total

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