| Literature DB >> 18294623 |
Céline Besset1, Stéphane Chambert, Yves Queneau, Sébastien Kerverdo, Hervé Rolland, Jérôme Guilbot.
Abstract
The reactivity of melezitose and raffinose under Mitsunobu conditions was studied within the scope of the use of trisaccharides for the synthesis of fatty acid esters. Melezitose led to esters with preferential substitution at primary positions following the order of reactivity 6''>6>6'. Raffinose proved to be very reluctant toward ester formation in these conditions, leading mainly to the new 3'',6''-anhydroraffinose.Entities:
Mesh：
Substances：
Year: 2008 PMID： 18294623 DOI： 10.1016/j.carres.2008.01.041
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104