Literature DB >> 18292897

Intramolecular cation-pi interactions control the conformation of nonrestricted (phenylalkyl)pyridines.

Isabella Richter1, Jusaku Minari, Philip Axe, John P Lowe, Tony D James, Kazuo Sakurai, Steven D Bull, John S Fossey.   

Abstract

NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular pi-stacking.

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Year:  2008        PMID： 18292897     DOI： 10.1039/b716937j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Ammonium catalyzed cyclitive additions: evidence for a cation-π interaction with alkynes.

Authors:  Edith Nagy; Elijah St Germain; Patrick Cosme; Pradip Maity; Andrew C Terentis; Salvatore D Lepore
Journal:  Chem Commun (Camb)       Date:  2016-02-07       Impact factor: 6.222

2.  Synthesis of medium-bridged twisted lactams via cation-pi control of the regiochemistry of the intramolecular Schmidt reaction.

Authors:  Michal Szostak; Lei Yao; Jeffrey Aubé
Journal:  J Org Chem       Date:  2010-02-19       Impact factor: 4.354

3.  Ethylenation of aldehydes to 3-propanal, propanol and propanoic acid derivatives.

Authors:  Daniel T Payne; Yiming Zhao; John S Fossey
Journal:  Sci Rep       Date:  2017-05-11       Impact factor: 4.379

4.  Intermolecular Charge-Transfer Luminescence by Self-Assembly of Pyridinium Luminophores in Solutions.

Authors:  Kaspars Leduskrasts; Edgars Suna
Journal:  ChemistryOpen       Date:  2021-10       Impact factor: 2.911
  4 in total

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