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Literature DB >> 18288665

Turning frustration into bond activation: a theoretical mechanistic study on heterolytic hydrogen splitting by frustrated Lewis pairs.

Tibor András Rokob¹, Andrea Hamza, András Stirling, Tibor Soós, Imre Pápai.

Abstract

Entities: Chemical

Mesh：

Substances：

Year: 2008 PMID： 18288665 DOI： 10.1002/anie.200705586

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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12 in total

1. A DFT study of hydrogen and methane activation by B(C₆F₅)₃/P(t-Bu)₃ and Al(C₆F₅)₃/P(t-Bu)₃ frustrated Lewis pairs.

Authors: Nery Villegas-Escobar; Alejandro Toro-Labbé; Marcos Becerra; Misael Real-Enriquez; Jose R Mora; Luis Rincon
Journal: J Mol Model Date: 2017-07-21 Impact factor: 1.810

2. On the hydrogen activation by frustrated Lewis pairs in the solid state: benchmark studies and theoretical insights.

Authors: Lei Liu; Jan Gerit Brandenburg; Stefan Grimme
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

3. Stabilizing a different cyclooctatetraene stereoisomer.

Authors: Longfei Li; Ming Lei; Yaoming Xie; Henry F Schaefer; Bo Chen; Roald Hoffmann
Journal: Proc Natl Acad Sci U S A Date: 2017-08-28 Impact factor: 11.205

4. Optimizing the Energetics of FLP-Type H₂ Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

Authors: Mojgan Heshmat; Bernd Ensing
Journal: J Phys Chem A Date: 2020-07-29 Impact factor: 2.781

5. Base-induced reversible H₂ addition to a single Sn(ii) centre.

Authors: Roland C Turnell-Ritson; Joshua S Sapsford; Robert T Cooper; Stella S Lee; Tamás Földes; Patricia A Hunt; Imre Pápai; Andrew E Ashley
Journal: Chem Sci Date: 2018-09-18 Impact factor: 9.825

6. A New Mode of Chemical Reactivity for Metal-Free Hydrogen Activation by Lewis Acidic Boranes.

Authors: Elliot L Bennett; Elliot J Lawrence; Robin J Blagg; Anna S Mullen; Fraser MacMillan; Andreas W Ehlers; Daniel J Scott; Joshua S Sapsford; Andrew E Ashley; Gregory G Wildgoose; J Chris Slootweg
Journal: Angew Chem Int Ed Engl Date: 2019-05-13 Impact factor: 15.336

Turning frustration into bond activation: a theoretical mechanistic study on heterolytic hydrogen splitting by frustrated Lewis pairs.

1. A DFT study of hydrogen and methane activation by B(C₆F₅)₃/P(t-Bu)₃ and Al(C₆F₅)₃/P(t-Bu)₃ frustrated Lewis pairs.

2. On the hydrogen activation by frustrated Lewis pairs in the solid state: benchmark studies and theoretical insights.

3. Stabilizing a different cyclooctatetraene stereoisomer.

4. Optimizing the Energetics of FLP-Type H₂ Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

5. Base-induced reversible H₂ addition to a single Sn(ii) centre.

6. A New Mode of Chemical Reactivity for Metal-Free Hydrogen Activation by Lewis Acidic Boranes.

7. Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation.

8. Metal-ligand multiple bonds as frustrated Lewis pairs for C-H functionalization.

9. Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

10. A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.