Literature DB >> 18284146

The pKa values of PFOA and other highly fluorinated carboxylic acids.

Kai-Uwe Goss1.   

Abstract

The dissociated and nondissociated species of any organic acid differ largely in their physicochemical behavior. The ratio of both species in aqueous systems is determined by the respective pKa value. For perfluorooctanoic acid recent fate-modeling studies have applied a pKa value of 2.8. This value likely is too high by 3 log units. Here, the correct value is estimated to be close to -0.5 based on analogy considerations and molecular modeling. Calculated pKa values for other highly fluorinated carboxylic acids are also presented.

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Year:  2008        PMID： 18284146     DOI： 10.1021/es702192c

Source DB:  PubMed          Journal:  Environ Sci Technol        ISSN： 0013-936X            Impact factor:   9.028


  22 in total

1.  Validation of quantitative measurements and semi-quantitative estimates of emerging perfluoroethercarboxylic acids (PFECAs) and hexfluoroprolyene oxide acids (HFPOAs).

Authors:  James McCord; Seth Newton; Mark Strynar
Journal:  J Chromatogr A       Date:  2018-03-23       Impact factor: 4.759

2.  Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface.

Authors:  Mark L Brusseau
Journal:  Sci Total Environ       Date:  2017-09-12       Impact factor: 7.963

3.  Distribution of perfluorinated compounds in drinking water treatment plant and reductive degradation by UV/SO32- process.

Authors:  Min Sun; Hao Zhou; Bei Xu; Junxin Bao
Journal:  Environ Sci Pollut Res Int       Date:  2017-12-26       Impact factor: 4.223

4.  Creating biocompatible oil-water interfaces without synthesis: direct interactions between primary amines and carboxylated perfluorocarbon surfactants.

Authors:  Cheryl J DeJournette; Joonyul Kim; Haley Medlen; Xiangpeng Li; Luke J Vincent; Christopher J Easley
Journal:  Anal Chem       Date:  2013-10-23       Impact factor: 6.986

Review 5.  Assessing the bioaccumulation potential of ionizable organic compounds: Current knowledge and research priorities.

Authors:  James M Armitage; Russell J Erickson; Till Luckenbach; Carla A Ng; Ryan S Prosser; Jon A Arnot; Kristin Schirmer; John W Nichols
Journal:  Environ Toxicol Chem       Date:  2016-12-19       Impact factor: 3.742

6.  On the swelling behavior of poly(N-Isopropylacrylamide) hydrogels exposed to perfluoroalkyl acids.

Authors:  Dustin T Savage; Nicolas J Briot; J Zach Hilt; Thomas D Dziubla
Journal:  J Polym Sci (2020)       Date:  2021-01-03

7.  High lipophilicity of perfluoroalkyl carboxylate and sulfonate: implications for their membrane permeability.

Authors:  Ping Jing; Patrick J Rodgers; Shigeru Amemiya
Journal:  J Am Chem Soc       Date:  2009-02-18       Impact factor: 15.419

8.  Mechanism of fatty-acid-dependent UCP1 uncoupling in brown fat mitochondria.

Authors:  Andriy Fedorenko; Polina V Lishko; Yuriy Kirichok
Journal:  Cell       Date:  2012-10-12       Impact factor: 41.582

9.  Efficient solubilization and purification of highly insoluble membrane proteins expressed as inclusion bodies using perfluorooctanoic acid.

Authors:  Sarah M Plucinsky; Kyle T Root; Kerney Jebrell Glover
Journal:  Protein Expr Purif       Date:  2017-10-21       Impact factor: 1.650

10.  Reactive Transport of U and V from Abandoned Uranium Mine Wastes.

Authors:  Sumant Avasarala; Peter C Lichtner; Abdul-Mehdi S Ali; Ricardo González-Pinzón; Johanna M Blake; José M Cerrato
Journal:  Environ Sci Technol       Date:  2017-10-24       Impact factor: 9.028
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