Literature DB >> 18275211

Preparation of functionalized alkylmagnesium derivatives using an I/Mg-exchange.

Christian B Rauhut1, Viet Anh Vu, Fraser F Fleming, Paul Knochel.   

Abstract

Functionalized alkylmagnesium reagents bearing an acetal, a ketal, an ester, or a pyridine ring were prepared by an I/Mg-exchange using iPr2Mg.LiCl or ClMg(CH2)5MgCl.2LiCl starting from functionalized primary alkyl iodides.

Entities:  

Year:  2008        PMID： 18275211     DOI： 10.1021/ol8000987

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Stereoselective synthesis of tetrasubstituted alkenes via a sequential carbocupration and a new sulfur-lithium exchange.

Authors:  Andreas Unsinn; Cora Dunst; Paul Knochel
Journal:  Beilstein J Org Chem       Date:  2012-12-18       Impact factor: 2.883

2.  Preparation of Primary and Secondary Dialkylmagnesiums by a Radical I/Mg-Exchange Reaction Using sBu2 Mg in Toluene.

Authors:  Alisa S Sunagatullina; Ferdinand H Lutter; Paul Knochel
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-09       Impact factor: 16.823
  2 in total

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