Literature DB >> 18266378

Gold-catalyzed intermolecular hetero-dehydro-diels-alder cycloaddition of captodative dienynes with nitriles: a new reaction and regioselective direct access to pyridines.

José Barluenga1, Manuel Angel Fernandez-Rodríguez, Patricia García-García, Enrique Aguilar.   

Abstract

For the first time, nitriles are used as 2pi electron component in a gold-catalyzed intermolecular hetero-dehydro-Diels-Alder cycloaddition with captodative enynes leading to the regioselective formation of pyridines.

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Year:  2008        PMID： 18266378     DOI： 10.1021/ja7112917

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.

Authors:  Todd K Hyster; Tomislav Rovis
Journal:  Chem Commun (Camb)       Date:  2011-10-10       Impact factor: 6.222

2.  Synthesis of azepines by a gold-catalyzed intermolecular [4 + 3]-annulation.

Authors:  Nathan D Shapiro; F Dean Toste
Journal:  J Am Chem Soc       Date:  2008-06-25       Impact factor: 15.419

3.  One-pot synthesis of highly functionalized pyridines via a rhodium carbenoid induced ring expansion of isoxazoles.

Authors:  James R Manning; Huw M L Davies
Journal:  J Am Chem Soc       Date:  2008-06-13       Impact factor: 15.419

4.  Recent developments in gold-catalyzed cycloaddition reactions.

Authors:  Fernando López; José L Mascareñas
Journal:  Beilstein J Org Chem       Date:  2011-08-09       Impact factor: 2.883

5.  Recent advances in the gold-catalyzed additions to C-C multiple bonds.

Authors:  He Huang; Yu Zhou; Hong Liu
Journal:  Beilstein J Org Chem       Date:  2011-07-04       Impact factor: 2.883

6.  Meeting the challenge of intermolecular gold(I)-catalyzed cycloadditions of alkynes and allenes.

Authors:  Michael E Muratore; Anna Homs; Carla Obradors; Antonio M Echavarren
Journal:  Chem Asian J       Date:  2014-07-22

7.  Computational exploration for possible reaction pathways, regioselectivity, and influence of substrate in gold-catalyzed cycloaddition of cyanamides with enynamides.

Authors:  Xinghui Zhang; Haixiong Shi; Caihong Ji; Jianyi Wang; Liping Jiang
Journal:  RSC Adv       Date:  2022-08-15       Impact factor: 4.036

8.  Metal-free intermolecular formal cycloadditions enable an orthogonal access to nitrogen heterocycles.

Authors:  Lan-Gui Xie; Supaporn Niyomchon; Antonio J Mota; Leticia González; Nuno Maulide
Journal:  Nat Commun       Date:  2016-03-15       Impact factor: 14.919

9.  Gold-catalyzed formal [4π + 2π]-cycloadditions of propiolate derivatives with unactivated nitriles.

Authors:  Somnath Narayan Karad; Wei-Kang Chung; Rai-Shung Liu
Journal:  Chem Sci       Date:  2015-07-20       Impact factor: 9.825
  9 in total

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