| Literature DB >> 18254641 |
Sarvesh Kumar1, Saravanan Peruncheralathan, Hiriyakkanavar Ila, Hiriyakkanavar Junjappa.
Abstract
A novel unexpected anionic domino process involving n-BuLi-induced rearrangement of 3,3-bis(methylthio) or 3-methylthio-3-aryl/heteroaryl/alkyl-o-bromoarylacrylonitriles to o-cyanoarylacetylenes in synthetically useful yields has been reported. The scope and generality of the reaction has been examined, and a possible mechanism has been proposed.Entities:
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Year: 2008 PMID： 18254641 DOI： 10.1021/ol800029c
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005