Literature DB >> 18253518

Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts. A mechanistic evaluation.

Maria-Héléna Gonçalves-Farbos1, Laurent Vial, Jérôme Lacour.   

Abstract

Using a supramolecular asymmetric ion pairing strategy, an enantioselective [1,2]-Stevens is feasible on substrates devoid of stereogenic quaternary nitrogen atoms.

Entities:  

Year:  2007        PMID： 18253518     DOI： 10.1039/b716488b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Biocatalytic One-Carbon Ring Expansion of Aziridines to Azetidines via a Highly Enantioselective [1,2]-Stevens Rearrangement.

Authors:  David C Miller; Ravi G Lal; Luca A Marchetti; Frances H Arnold
Journal:  J Am Chem Soc       Date:  2022-03-08       Impact factor: 16.383

2.  Investigations Concerning the Syntheses of TADDOL-Derived Secondary Amines and Their Use To Access Novel Chiral Organocatalysts.

Authors:  Katharina Gratzer; Mario Waser
Journal:  Synthesis (Stuttg)       Date:  2012-12       Impact factor: 3.157
  2 in total

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