Literature DB >> 18253010

Cyclopentadecanone.

Eric A Noe1, Diwakar M Pawar, Frank R Fronczek.   

Abstract

In the crystal structure, the title compound (exaltone), C(15)H(28)O, exhibits no disorder, and the 15-membered ring exists in the quinquangular [13353] C(1) symmetry conformation. The crystal exhibits nonmerohedral twinning by twofold rotation about [100], but adjustment of the temperature to 90 K causes the [101] distance to equal the c axial length, allowing the twinning to be treated as pseudo-merohedral. The literature description of the structure as disordered orthorhombic with halved a-axis length is corrected.

Entities:  

Year:  2008        PMID: 18253010     DOI: 10.1107/S0108270107066139

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  Conformational analysis of thioether musks using density functional theory.

Authors:  William N Setzer
Journal:  Int J Mol Sci       Date:  2009-08-04       Impact factor: 5.923

2.  Pseudomerohedrally twinned monoclinic structure of unfolded 'free' nonactin: comparative analysis of its large conformational change upon encapsulation of alkali metal ions.

Authors:  Ilia A Guzei; Cheng Wang; Yulian Zhan; Oleg V Dolomanov; Yi-Qiang Cheng
Journal:  Acta Crystallogr C       Date:  2009-09-19       Impact factor: 1.172

  2 in total

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