Literature DB >> 18252990

catena-Poly[[[(benzene-1,3,5-tricarboxylic acid)(1,10-phenanthroline)cadmium(II)]-micro-oxalato] 1H-benzotriazole solvate monohydrate].

Chao Qin1, Xin-Long Wang, En-Bo Wang.   

Abstract

In the title compound, [Cd(C(2)O(4))(C(12)H(8)N(2))(C(9)H(6)O(6))].C(6)H(5)N(3).H(2)O, the Cd(II) atom has a distorted pentagonal-bipyramidal geometry, defined by two N atoms and five O atoms from bidentate 1,10-phenanthroline ligands, oxalate ligands and benzene-1,3,5-tricarboxylic acid ligands. The oxalate ligands in the asymmetric unit possess inversion symmetry. The triazole molecule is not coordinated to the Cd atom. The structure of the title compound features a one-dimensional chain running along the crystallographic a axis, and a three-dimensional supramolecular network is formed via aromatic pi-pi interactions and hydrogen-bonding interactions.

Entities:  

Year:  2008        PMID: 18252990     DOI: 10.1107/S0108270107064578

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Bis(μ-6-hydroxy-naphthalene-1-carboxyl-ato)bis-[(6-hydroxy-naphthalene-1-car-box-yl-ato)(1,10-phenanthroline)cadmium(II)] tetra-hydrate.

Authors:  Chun-Sen Liu; Min Hu; Liang-Qi Guo
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-10-28
  1 in total

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