| Literature DB >> 18248000 |
Akihiko Matsuyama1, Ryota Hirashima.
Abstract
We present a mean-field theory to describe phase separations in mixtures of a nematic liquid crystal and a colloidal particle. The theory takes into account an orientational ordering of liquid crystals and a crystalline ordering of colloidal particles. We calculate phase diagrams on the temperature-concentration plane, depending on interactions between a liquid crystal and a colloidal surface and a coupling between nematic and crystalline ordering. We find various phase separation processes, such as a nematic-crystal phase separation and nematic-isotropic-crystal triple point. Inside binodal curves, we find new unstable and metastable regions which are important in phase ordering dynamics. We also find a stable nematic-crystalline (NC) phase, where colloidal particles dispersed in a nematic phase can form a crystalline structure. The coexistence between two NC phases with different concentrations can be appear though the coupling between nematic and crystalline ordering.Mesh:
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Year: 2008 PMID: 18248000 DOI: 10.1063/1.2823737
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488