Literature DB >> 18237182

Rh(II)-catalyzed Sommelet-Hauser rearrangement.

Mingyi Liao1, Lingling Peng, Jianbo Wang.   

Abstract

Catalytic Sommelet-Hauser rearrangement is reported. The Rh(II)-catalyzed reaction of aryldiazoacetates with ethyl benzylthioacetate affords Sommelet-Hauser rearrangement products in good to excellent yields. This reaction provides a reliable and efficient way to introduce a substituent to the ortho position of arylacetates.

Entities:  

Year:  2008        PMID： 18237182     DOI： 10.1021/ol703058p

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

2.  Combined inorganic base promoted N-addition/[2,3]-sigmatropic rearrangement to construct homoallyl sulfur-containing pyrazolones.

Authors:  Shou-Jie Shen; Xiao-Li Du; Xiao-Li Xu; Yue-Hua Wu; Ming-Gang Zhao; Jin-Yan Liang
Journal:  RSC Adv       Date:  2019-10-29       Impact factor: 4.036

3.  One-pot synthesis of highly functionalized pyridines via a rhodium carbenoid induced ring expansion of isoxazoles.

Authors:  James R Manning; Huw M L Davies
Journal:  J Am Chem Soc       Date:  2008-06-13       Impact factor: 15.419

Review 4.  Sulfur-Based Ylides in Transition-Metal-Catalysed Processes.

Authors:  James D Neuhaus; Rik Oost; Jérémy Merad; Nuno Maulide
Journal:  Top Curr Chem (Cham)       Date:  2018-04-13

5.  Catalyst-Controlled Regiodivergence in Rearrangements of Indole-Based Onium Ylides.

Authors:  Vaishnavi N Nair; Volga Kojasoy; Croix J Laconsay; Wang Yeuk Kong; Dean J Tantillo; Uttam K Tambar
Journal:  J Am Chem Soc       Date:  2021-06-14       Impact factor: 16.383
  5 in total

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