Literature DB >> 18233535

Incommensurate charge order phase in Fe2OBO3 due to geometrical frustration.

M Angst1, R P Hermann, W Schweika, J-W Kim, P Khalifah, H J Xiang, M-H Whangbo, D-H Kim, B C Sales, D Mandrus.   

Abstract

The temperature dependence of charge order in Fe2OBO3 was investigated by resistivity and differential scanning calorimetry measurements, Mössbauer spectroscopy, and synchrotron x-ray scattering, revealing an intermediate phase between room temperature and 340 K, characterized by coexisting mobile and immobile carriers, and by incommensurate superstructure modulations with temperature-dependent propagation vector (1/2, 0, tau). The incommensurate modulations arise from specific antiphase boundaries with low energy cost due to geometrical charge frustration.

Entities:  

Year:  2007        PMID: 18233535     DOI: 10.1103/PhysRevLett.99.256402

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  2 in total

1.  Charge-ordering transition in iron oxide Fe4O5 involving competing dimer and trimer formation.

Authors:  Sergey V Ovsyannikov; Maxim Bykov; Elena Bykova; Denis P Kozlenko; Alexander A Tsirlin; Alexander E Karkin; Vladimir V Shchennikov; Sergey E Kichanov; Huiyang Gou; Artem M Abakumov; Ricardo Egoavil; Johan Verbeeck; Catherine McCammon; Vadim Dyadkin; Dmitry Chernyshov; Sander van Smaalen; Leonid S Dubrovinsky
Journal:  Nat Chem       Date:  2016-04-04       Impact factor: 24.427

Review 2.  Magnetism and the Trimeron Bond.

Authors:  J Paul Attfield
Journal:  Chem Mater       Date:  2022-03-30       Impact factor: 10.508

  2 in total

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