| Literature DB >> 18229933 |
Philippe Bertus1, Christine Menant, Chloé Tanguy, Jan Szymoniak.
Abstract
It has been shown that diene-titanium complexes exhibit substrate-dependent 1,2- or 1,4-dicarbanion reactivity. On this basis, 3-cyclopentenylamines and spiro-vinylcyclopropane lactams were easily prepared by using homoallylic Grignard reagents, Ti(O-i-Pr)4, and nitriles or cyanoesters, respectively.Entities:
Year: 2008 PMID： 18229933 DOI： 10.1021/ol702917c
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005