Computer analyses of new numerical methods for the description of adsorption process and the reliability of identification of microporous structure parameters.

The aim of this work was the computer analysis of numerical properties of the original mathematical method of the description of adsorption process and the reliability of the identification of structure parameters. The method is based on the theory of multilayer adsorption, the derivation and further theoretical discussion of which was presented in the author's earlier works. The following tasks were given special attention in this paper: the influence of the assumed structure parameters, the influence of the high-pressure section of adsorption isotherms and the influence of the number of simultaneously fitted adsorption isotherms on the quality of identification and the errors of microporous structure parameters. This research provides a basis for the evaluation of the reliability of the parameters calculated for real adsorption systems.