Literature DB >> 18219410

Highly efficient and stereoselective synthesis of beta-glycolipids.

José Antonio Morales-Serna1, Omar Boutureira, Yolanda Díaz, M Isabel Matheu, Sergio Castillón.   

Abstract

beta-Galactosylceramide and glycolipid analogues were prepared in high yield and with complete chemo and stereoselectivity by reaction of alpha-iodo glycosides with stannyl ceramides, formed in situ. TBAI was used to activate both the iodogalactose and the stannyl ether.

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Year:  2007        PMID： 18219410     DOI： 10.1039/b718521a

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  2 in total

1.  Two-step functionalization of oligosaccharides using glycosyl iodide and trimethylene oxide and its applications to multivalent glycoconjugates.

Authors:  Hsiao-Wu Hsieh; Ryan A Davis; Jessica A Hoch; Jacquelyn Gervay-Hague
Journal:  Chemistry       Date:  2014-04-08       Impact factor: 5.236

2.  Integrating ReSET with glycosyl iodide glycosylation in step-economy syntheses of tumor-associated carbohydrate antigens and immunogenic glycolipids.

Authors:  Hsiao-Wu Hsieh; Matthew W Schombs; Jacquelyn Gervay-Hague
Journal:  J Org Chem       Date:  2014-02-07       Impact factor: 4.354
  2 in total

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