| Literature DB >> 18209806 |
Melanie Zimmermann1, Josef Takats, Gong Kiel, Karl W Törnroos, Reiner Anwander.
Abstract
The reaction of Ln(AlMe(4))(3) with bulky hydrotris(pyrazolyl)borate (Tp(t)(Bu,Me))H proceeds via a sequence of methane elimination and C-H bond activation, affording unprecedented rare-earth metal ligand moieties including Ln(Me)[(micro-Me)AlMe(3)] and X-ray structurally characterized "Tebbe-like" Ln[(micro-CH(2))(2)AlMe(2)].Entities:
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Year: 2007 PMID： 18209806 DOI： 10.1039/b713378b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222