Literature DB >> 18198827

Facile synthesis of the tridecameric Al13 nanocluster Al13(mu3-OH)6(mu2-OH)18(H2O)24(NO3)15.

Jason T Gatlin1, Zachary L Mensinger, Lev N Zakharov, David Macinnes, Darren W Johnson.   

Abstract

Treatment of aluminum nitrate with an organic nitroso-containing compound yields the "flat", tridecameric nanocluster Al 13(mu 3-OH) 6(mu 2-OH) 18(H 2O) 24(NO 3) 15 ( Al 13 ) in good yield on a preparative scale under ambient conditions. Synthetic procedures yielding two different single-crystal forms of the Al 13 cation with two varying counterion compositions are described.

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Year:  2008        PMID: 18198827     DOI: 10.1021/ic7020808

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  2 in total

1.  Electrolytic synthesis of aqueous aluminum nanoclusters and in situ characterization by femtosecond Raman spectroscopy and computations.

Authors:  Wei Wang; Weimin Liu; I-Ya Chang; Lindsay A Wills; Lev N Zakharov; Shannon W Boettcher; Paul Ha-Yeon Cheong; Chong Fang; Douglas A Keszler
Journal:  Proc Natl Acad Sci U S A       Date:  2013-10-28       Impact factor: 11.205

2.  Errors in the calculation of (27)Al nuclear magnetic resonance chemical shifts.

Authors:  Xianlong Wang; Chengfei Wang; Hui Zhao
Journal:  Int J Mol Sci       Date:  2012-11-21       Impact factor: 5.923

  2 in total

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