| Literature DB >> 18198827 |
Jason T Gatlin1, Zachary L Mensinger, Lev N Zakharov, David Macinnes, Darren W Johnson.
Abstract
Treatment of aluminum nitrate with an organic nitroso-containing compound yields the "flat", tridecameric nanocluster Al 13(mu 3-OH) 6(mu 2-OH) 18(H 2O) 24(NO 3) 15 ( Al 13 ) in good yield on a preparative scale under ambient conditions. Synthetic procedures yielding two different single-crystal forms of the Al 13 cation with two varying counterion compositions are described.Entities:
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Year: 2008 PMID: 18198827 DOI: 10.1021/ic7020808
Source DB: PubMed Journal: Inorg Chem ISSN: 0020-1669 Impact factor: 5.165