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Literature DB >> 18188479

Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N(3)P(3)Cl(6)] catalyzed by silylium ions.

Yun Zhang¹, Keith Huynh, Ian Manners, Christopher A Reed.

Abstract

The temperature required for ring-opening polymerisation of cyclo-N(3)P(3)Cl(6) can be dramatically lowered by employing trialkylsilylium carboranes [R(3)Si(CHB(11)X(11)] as catalysts.

Entities: Chemical

Year: 2007 PMID： 18188479 DOI： 10.1039/b713933k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

2 in total

1. H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Authors: Christopher A Reed
Journal: Acc Chem Res Date: 2010-01-19 Impact factor: 22.384

2. Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes.

Authors: Helena Henke; Sandra Posch; Oliver Brüggemann; Ian Teasdale
Journal: Macromol Rapid Commun Date: 2016-03-29 Impact factor: 5.734

2 in total