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Literature DB >> 18165952

(Me3Si)3SiH: twenty years after its discovery as a radical-based reducing agent.

Abstract

This Concept shows the flexibility and applicability of (Me3Si)3SiH in several synthetic transformations, such as radical reductions, consecutive radical reactions and hydrosilylation. The reactivity of (Me3Si)3SiH combines the multidisciplinary aspects of physical organic chemistry and organic synthesis, extending to polymers and materials science, as in the functionalization of flat silicon surfaces.

Entities: Chemical

Year: 2008 PMID： 18165952 DOI： 10.1002/chem.200701415

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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Cited

11 in total

1. Application of germyldesulfonylation reactions to the synthesis of germanium-containing nucleoside analogues.

Authors: Stanislaw F Wnuk; Pablo R Sacasa; Jorge Restrepo
Journal: Nucleosides Nucleotides Nucleic Acids Date: 2009-05 Impact factor: 1.381

2. Sustainable Protocol for the Synthesis of 2',3'-Dideoxynucleoside and 2',3'-Didehydro-2',3'-dideoxynucleoside Derivatives.

Authors: Virginia Martín-Nieves; Yogesh S Sanghvi; Susana Fernández; Miguel Ferrero
Journal: Molecules Date: 2022-06-21 Impact factor: 4.927

3. Tin-free enantioselective radical reactions using silanes.

Authors: Mukund P Sibi; Yong-Hua Yang; Sunggi Lee
Journal: Org Lett Date: 2008-12-04 Impact factor: 6.005

4. Carbene-Stabilized Main Group Radicals and Radical Ions.

Authors: Caleb D Martin; Michele Soleilhavoup; Guy Bertrand
Journal: Chem Sci Date: 2013-08-01 Impact factor: 9.825

5. Diastereoselective Synthesis of 6″-(Z)- and 6″-(E)-Fluoro Analogues of Anti-hepatitis B Virus Agent Entecavir and Its Evaluation of the Activity and Toxicity Profile of the Diastereomers.

Authors: Hiroki Kumamoto; Misato Fukano; Tomohiko Nakano; Keito Iwagami; Chiaki Takeyama; Satoru Kohgo; Shuhei Imoto; Masayuki Amano; Nobuyo Kuwata-Higashi; Manabu Aoki; Hiroshi Abe; Hiroaki Mitsuya; Kiyoshi Fukuhara; Kazuhiro Haraguchi
Journal: J Org Chem Date: 2016-03-24 Impact factor: 4.354

10. A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes.

Authors: Maxim Ratushnyy; Monika Kamenova; Vladimir Gevorgyan
Journal: Chem Sci Date: 2018-07-25 Impact factor: 9.825

(Me3Si)3SiH: twenty years after its discovery as a radical-based reducing agent.

1. Application of germyldesulfonylation reactions to the synthesis of germanium-containing nucleoside analogues.

2. Sustainable Protocol for the Synthesis of 2',3'-Dideoxynucleoside and 2',3'-Didehydro-2',3'-dideoxynucleoside Derivatives.

3. Tin-free enantioselective radical reactions using silanes.

4. Carbene-Stabilized Main Group Radicals and Radical Ions.

5. Diastereoselective Synthesis of 6″-(Z)- and 6″-(E)-Fluoro Analogues of Anti-hepatitis B Virus Agent Entecavir and Its Evaluation of the Activity and Toxicity Profile of the Diastereomers.

6. Au(I)-catalyzed ring expanding cycloisomerizations: total synthesis of ventricosene.

7. Nature's hydrides: rapid reduction of halocarbons by folate model compounds.

Review 8. Recent applications of the (TMS)3SiH radical-based reagent.

9. Preparation of optically active bicyclodihydrosiloles by a radical cascade reaction.

10. A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes.