Literature DB >> 18092793

(BDP)CuH: a "hot" Stryker's reagent for use in achiral conjugate reductions.

Benjamin A Baker1, Zarko V Bosković, Bruce H Lipshutz.   

Abstract

A ligand-modified, economical version of Stryker's reagent (SR) has been developed based on a bidentate, achiral bis-phosphine. Generated in situ, "(BDP)CuH" smoothly effects conjugate reductions of a variety of unsaturated substrates, including those that are normally unreactive toward SR. Substrate-to-ligand ratios typically on the order of 1000-10000:1 can be used leading to products in high yields.

Entities:  

Year:  2007        PMID： 18092793     DOI： 10.1021/ol702689v

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  11 in total

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