Literature DB >> 18060151

A Lewis-basic, dionio-substituted phosphane.

Martyn P Coles1, Peter B Hitchcock.   

Abstract

Bis{guanidine} H(2)C{hpp}(2)[hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine] reacts with PPhCl(2) to generate the dionio-substituted phosphane, [H(2)C{hpp}(2)PPh](2+)[Cl](-)(2) which, despite the formally dicationic phosphorus centre, forms an unprecedented coordination compound with platinum.

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Year:  2007        PMID: 18060151     DOI: 10.1039/b710923g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Redox non-innocence of a N-heterocyclic nitrenium cation bound to a nickel-cyclam core.

Authors:  Florian Heims; Florian Felix Pfaff; Sarah-Luise Abram; Erik R Farquhar; Maurizio Bruschi; Claudio Greco; Kallol Ray
Journal:  J Am Chem Soc       Date:  2013-12-31       Impact factor: 15.419

  1 in total

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