Literature DB >> 18057606

Diaquabis(quinoxaline-2-carboxylato-kappa2N1,O)copper(II).

Yue Feng1, Gang Liu, Xiu-Mei Tian, Ji-De Wang.   

Abstract

In the title compound, [Cu(C9H5N2O2)2(H2O)2], the Cu(II) ion lies on an inversion centre and has an elongated centrosymmetric octahedral environment, equatorially trans-coordinated by two N,O-bidentate quinoxaline-2-carboxylate ligands and axially coordinated by two water O atoms. Symmetry-related molecules are linked by strong O-H...O hydrogen bonds, involving the uncoordinated carboxyl O atom of the carboxylate group and the coordinated water molecules, to form a two-dimensional network. Weak intermolecular C-H...N interactions also stabilize the crystal structure.

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Year:  2007        PMID: 18057606     DOI: 10.1107/S0108270107053723

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Tetra-ethyl-ammonium tricarbonyl-chlorido(quinoxaline-2-carboxyl-ato-κN,O)rhenate(I).

Authors:  Janine Suthiram; Jan Rijn Zeevaart; Hendrik G Visser; Andreas Roodt
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-07-31
  1 in total

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