Literature DB >> 18049758

Liquid crystals carrying stereodefined vicinal difluoro- and trifluoro- alkyl motifs.

Marcello Nicoletti1, Matthias Bremer, Peer Kirsch, David O'Hagan.   

Abstract

The synthesis of the stereospecifically fluorinated difluoro- and trifluoro- rac-3 and rac-4 is described where the fluorine atoms are positioned adjacent/vicinal to each other and the physical characteristics of these candidate liquid crystals including negative dielectric anisotropy are measured and rationalised.

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Year:  2007        PMID: 18049758     DOI: 10.1039/b711839b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Three step synthesis of single diastereoisomers of the vicinal trifluoro motif.

Authors:  Vincent A Brunet; Alexandra M Z Slawin; David O'Hagan
Journal:  Beilstein J Org Chem       Date:  2009-11-05       Impact factor: 2.883

2.  The C-F bond as a conformational tool in organic and biological chemistry.

Authors:  Luke Hunter
Journal:  Beilstein J Org Chem       Date:  2010-04-20       Impact factor: 2.883

3.  Synthesis and crystallographic analysis of meso-2,3-difluoro-1,4-butanediol and meso-1,4-dibenzyloxy-2,3-difluorobutane.

Authors:  Bruno Linclau; Leo Leung; Jean Nonnenmacher; Graham Tizzard
Journal:  Beilstein J Org Chem       Date:  2010-06-08       Impact factor: 2.883

4.  Can acyclic conformational control be achieved via a sulfur-fluorine gauche effect?

Authors:  C Thiehoff; M C Holland; C Daniliuc; K N Houk; R Gilmour
Journal:  Chem Sci       Date:  2015-04-17       Impact factor: 9.825

  4 in total

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