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Literature DB >> 18049757

Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct.

Patrick Spies¹, Gerhard Erker, Gerald Kehr, Klaus Bergander, Roland Fröhlich, Stefan Grimme, Douglas W Stephan.

Abstract

A four-membered cyclic intramolecular phosphane-borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium-hydridoborate system, which reduces benzaldehyde.

Entities: Chemical

Mesh：

Substances：

Year: 2007 PMID： 18049757 DOI： 10.1039/b710475h

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

27 in total

1. Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

Authors: Kantapat Chansaenpak; Mengxi Yang; François P Gabbaï
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

2. Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

Authors: Jennifer Möricke; Birgit Wibbeling; Constantin G Daniliuc; Gerald Kehr; Gerhard Erker
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

Review 3. On the concept of frustrated Lewis pairs.

Authors: Frédéric-Georges Fontaine; Douglas W Stephan
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

4. Chemical reactivity of the frustrated Lewis pairs in borophosphines: a theoretical analysis of their Lewis acidity, Lewis basicity and Fukui function.

Authors: Mariano Méndez; Andrés Cedillo
Journal: J Mol Model Date: 2018-08-17 Impact factor: 1.810

5. Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols.

Authors: Hua Zhang; Xiao-Yu Zhan; Yu Dong; Jian Yang; Shuai He; Zhi-Chuan Shi; Xiao-Mei Zhang; Ji-Yu Wang
Journal: RSC Adv Date: 2020-04-30 Impact factor: 4.036

6. A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.

Authors: Elliot J Lawrence; Robin J Blagg; David L Hughes; Andrew E Ashley; Gregory G Wildgoose
Journal: Chemistry Date: 2014-11-07 Impact factor: 5.236

Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct.

1. Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

2. Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

Review 3. On the concept of frustrated Lewis pairs.

4. Chemical reactivity of the frustrated Lewis pairs in borophosphines: a theoretical analysis of their Lewis acidity, Lewis basicity and Fukui function.

5. Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols.

6. A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.

7. A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes.

8. Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid.

9. Tri-insertion with dearomatization of terminal arylalkynes using a carborane based frustrated Lewis pair template.

10. A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C-X (X=Cl, Br) Bond Activation.