Literature DB >> 18049745

Tetravalent cerium carbene complexes.

Ian J Casely1, Stephen T Liddle, Alexander J Blake, Claire Wilson, Polly L Arnold.   

Abstract

The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L=a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.

Entities:  

Year:  2007        PMID: 18049745     DOI: 10.1039/b713041d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  The duality of electron localization and covalency in lanthanide and actinide metallocenes.

Authors:  Danil E Smiles; Enrique R Batista; Corwin H Booth; David L Clark; Jason M Keith; Stosh A Kozimor; Richard L Martin; Stefan G Minasian; David K Shuh; S Chantal E Stieber; Tolek Tyliszczak
Journal:  Chem Sci       Date:  2020-02-05       Impact factor: 9.825

2.  The role of dynamic ligand exchange in the oxidation chemistry of cerium(iii).

Authors:  Jerome R Robinson; Yusen Qiao; Jun Gu; Patrick J Carroll; Patrick J Walsh; Eric J Schelter
Journal:  Chem Sci       Date:  2016-03-23       Impact factor: 9.825

3.  Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift.

Authors:  Grace B Panetti; Dumitru-Claudiu Sergentu; Michael R Gau; Patrick J Carroll; Jochen Autschbach; Patrick J Walsh; Eric J Schelter
Journal:  Nat Commun       Date:  2021-03-17       Impact factor: 14.919

4.  Tungsten(VI) N-Heterocyclic Carbene Complexes: Synthetic, Structural, and Computational Study.

Authors:  Christopher A Dodds; Mark D Spicer; Tell Tuttle
Journal:  Organometallics       Date:  2011-11-03       Impact factor: 3.876

  4 in total

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