Periodically poled BaMgF(4) for ultraviolet frequency generation.

Ferroelectric domain inversion has been demonstrated in BaMgF(4) . Transparency has been measured to <140nm, and no change in transmission was measured under 157-nm irradiation for >1.1x10(9) shots at 2mJ/cm(2) per pulse. First-order quasi-phase-matched generation of 157 nm is predicted by use of grating periods as long as 1.5mum. This material should permit shorter-wavelength chi((2)) frequency-mixing processes than with any other crystalline material.