Literature DB >> 18043796

Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)-Cu(OAc)2.H2O complex.

Sandeep K Ginotra1, Vinod K Singh.   

Abstract

A C(2)-symmetric diethyl (i)Pr-bis(oxazoline)-Cu(OAc)(2).H(2)O was found to be an efficient catalyst for catalyzing an enantioselective Henry reaction between nitromethane and various aldehydes to provide beta-hydroxy nitroalkanes with high chemical yields (up to 95%) and enantiomeric excesses (up to 97%).

Entities:  

Year:  2007        PMID: 18043796     DOI: 10.1039/b714153j

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  Synthesis and Catalytic Application of Two Mononuclear Complexes Bearing Diethylenetriamine Derivative Ligand.

Authors:  Chao Liu; Zhao Yang; Hao Guo; Yu-Cai Zhao
Journal:  Molecules       Date:  2020-04-30       Impact factor: 4.411

2.  Cu (II)-catalyzed asymmetric henry reaction with a novel C1-symmetric aminopinane-derived ligand.

Authors:  Liudmila Filippova; Yngve Stenstrøm; Trond Vidar Hansen
Journal:  Molecules       Date:  2015-04-09       Impact factor: 4.411

  2 in total

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