| Literature DB >> 18007440 |
Abstract
The use of iodobenzene diacetate and iodine under photolytic conditions provides and efficient method for the oxidative cyclization of spiroacetals bearing an hydroxyalkyl side chain to bis-spiroacetals. An overview is provided of the use of this reaction for the synthesis of several bis-spiroacetal containing natural products such as the polyether antibiotics salinomycin and CP44,161 and the shellfish toxins, the spirolides.Entities:
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Year: 2004 PMID： 18007440 PMCID： PMC6147298 DOI： 10.3390/90600394
Source DB: PubMed Journal: Molecules ISSN： 1420-3049 Impact factor: 4.411