Literature DB >> 18007430

Investigations into the use of a polyfluorooctanol as an auxiliary component for an aldol reaction.

Jason Eames1, Hasina Khanom.   

Abstract

Results are reported on the efficiency of polyfluorooctanol as a perfluorous auxiliary component in the aldol reaction between the enolate derived from polyfluorooctyl acetate and 2-fluorobenzaldehyde. Reduction of the corresponding polyfluoro beta-hydroxy ester with Super Hydride gave the required 1,3-diol in good yield.

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Year:  2004        PMID： 18007430      PMCID： PMC6147310          DOI： 10.3390/90500266

Source DB:  PubMed          Journal:  Molecules        ISSN： 1420-3049            Impact factor:   4.411


  5 in total

1.  The aldol addition reaction: an old transformation at constant rebirth.

Authors:  Claudio Palomo; Mikel Oiarbide; Jesús M García
Journal:  Chemistry       Date:  2002-01-04       Impact factor: 5.236

2.  Modern separation techniques for the efficient workup in organic synthesis.

Authors:  Carl Christoph Tzschucke; Christian Markert; Willi Bannwarth; Sebastian Roller; André Hebel; Rainer Haag
Journal:  Angew Chem Int Ed Engl       Date:  2002-11-04       Impact factor: 15.336

3.  Practical and highly selective oxazolidinethione-based asymmetric acetate aldol reactions with aliphatic aldehydes.

Authors:  Nathan R Guz; Andrew J Phillips
Journal:  Org Lett       Date:  2002-06-27       Impact factor: 6.005

4.  Fluorous synthesis: a fluorous-phase strategy for improving separation efficiency in organic synthesis.

Authors:  A Studer; S Hadida; R Ferritto; S Y Kim; P Jeger; P Wipf; D P Curran
Journal:  Science       Date:  1997-02-07       Impact factor: 47.728

5.  Studies directed toward the total synthesis of discodermolide: asymmetric synthesis of the C1-C14 fragment.

Authors:  Alexander Arefolov; James S Panek
Journal:  Org Lett       Date:  2002-07-11       Impact factor: 6.005
  5 in total

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