Literature DB >> 17999494

Electrochemical and EPR studies of the corannulene ruthenium(II) sandwich complex [(eta6-C6Me6)Ru(eta6-C20H10)](SbF6)(2).

Robert J Angelici1, Bolin Zhu, Serena Fedi, Franco Laschi, Piero Zanello.   

Abstract

The dication [(eta6-C6Me6)Ru(eta6-C20H10)]2+ in propylene carbonate solution exhibits a sequence of reduction processes that is either metal-centered [Ru(II)/Ru(I)/Ru(0)] or ligand-centered. The marginally stable Ru(I) monocation [(eta6-C6Me6)Ru(eta6-C20H10)]+ has been characterized by EPR spectroscopy. The electrochemistry of C20H10 and EPR features of its stable monoanion [C20H10]- have also been revisited.

Entities:  

Year:  2007        PMID： 17999494     DOI： 10.1021/ic7015512

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  4 in total

1.  Access to well-defined ruthenium(I) and osmium(I) metalloradicals.

Authors:  Ayumi Takaoka; Laura C H Gerber; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2010-06-01       Impact factor: 15.336

2.  Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes.

Authors:  Javier Fajardo; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2017-11-02       Impact factor: 15.419

3.  Sweetening ruthenium and osmium: organometallic arene complexes containing aspartame.

Authors:  Jennifer C Gray; Abraha Habtemariam; Marcel Winnig; Wolfgang Meyerhof; Peter J Sadler
Journal:  J Biol Inorg Chem       Date:  2008-06-13       Impact factor: 3.358

4.  Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole-Based Tripodal Tetraphosphine Ligand.

Authors:  Fenna F van de Watering; Jarl Ivar van der Vlugt; Wojciech I Dzik; Bas de Bruin; Joost N H Reek
Journal:  Chemistry       Date:  2017-08-30       Impact factor: 5.236
  4 in total

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