Literature DB >> 17997577

The mechanism of TBD-catalyzed ring-opening polymerization of cyclic esters.

Luis Simón1, Jonathan M Goodman.   

Abstract

Triazabicyclodecene (TBD) has recently been shown to be an effective organocatalyst for the ring-opening polymerization (ROP) of cyclic esters. Using DFT methods, we have studied possible mechanisms of this reaction. Our studies explain not only the narrow polydispersity index (PDI) observed in the ROP of six-membered ring lactones, but also the surprising failure of the ROP for the more reactive butyrolactone.

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Year:  2007        PMID： 17997577     DOI： 10.1021/jo702088c

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  10 in total

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5.  Tuning Properties of Poly(ethylene glycol)-block-poly(simvastatin) Copolymers Synthesized via Triazabicyclodecene.

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7.  Complexities of Regioselective Ring-Opening vs Transcarbonylation-Driven Structural Metamorphosis during Organocatalytic Polymerizations of Five-Membered Cyclic Carbonate Glucose Monomers.

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8.  Nanoformulation-by-design: an experimental and molecular dynamics study for polymer coated drug nanoparticles.

Authors:  Ioanna Danai Styliari; Vincenzo Taresco; Andrew Theophilus; Cameron Alexander; Martin Garnett; Charles Laughton
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Authors:  Ning Zhu; Yihuan Liu; Junhua Liu; Jun Ling; Xin Hu; Weijun Huang; Weiyang Feng; Kai Guo
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10.  TBD- or PS-TBD-Catalyzed One-Pot Synthesis of Cyanohydrin Carbonates and Cyanohydrin Acetates from Carbonyl Compounds.

Authors:  Satoru Matsukawa; Junya Kimura; Miki Yoshioka
Journal:  Molecules       Date:  2016-08-10       Impact factor: 4.411
  10 in total

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