Literature DB >> 17997570

One-pot reductive mono-N-alkylation of aniline and nitroarene derivatives using aldehydes.

Eunyoung Byun1, Bomi Hong, Kathlia A De Castro, Minkyung Lim, Hakjune Rhee.   

Abstract

One-pot reductive mono-N-alkylation of aniline and nitroarene derivatives using various aldehydes by Pd/C catalyst in aqueous 2-propanol solvent with ammonium formate as in situ hydrogen donor is illustrated. The reaction proceeded smoothly and selectively with excellent yield at room temperature. Our protocol presents a facile, economical, and environmentally benign alternative for reductive amination.

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Year:  2007        PMID： 17997570     DOI： 10.1021/jo701503q

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  9 in total

1.  Modified synthesis of erlotinib hydrochloride.

Authors:  Leila Barghi; Ayuob Aghanejad; Hadi Valizadeh; Jaleh Barar; Davoud Asgari
Journal:  Adv Pharm Bull       Date:  2012-05-05

2.  Reductive N-alkylation of nitroarenes: a green approach for the N-alkylation of natural products.

Authors:  Amir E Wahba; Mark T Hamann
Journal:  J Org Chem       Date:  2012-04-30       Impact factor: 4.354

Review 3.  Methods for Direct Reductive N-Methylation of Nitro Compounds.

Authors:  Zhijie Jiang; Evan Abdulkareem Mahmood; Nazanin Zare Harofteh; Abdol Ghaffar Ebadi; Mohsen Toughani; Esmail Vessally
Journal:  Top Curr Chem (Cham)       Date:  2022-05-24

4.  Mechanochemical Catalytic Transfer Hydrogenation of Aromatic Nitro Derivatives.

Authors:  Tomislav Portada; Davor Margetić; Vjekoslav Štrukil
Journal:  Molecules       Date:  2018-11-30       Impact factor: 4.411

Review 5.  Catalytic Reductive Amination of Aldehydes and Ketones With Nitro Compounds: New Light on an Old Reaction.

Authors:  Alexey Yu Sukhorukov
Journal:  Front Chem       Date:  2020-04-15       Impact factor: 5.221

Review 6.  Metal-based Heterogeneous Catalysts for One-Pot Synthesis of Secondary Anilines from Nitroarenes and Aldehydes.

Authors:  Giuseppe Romanazzi; Valentina Petrelli; Ambra Maria Fiore; Piero Mastrorilli; Maria Michela Dell'Anna
Journal:  Molecules       Date:  2021-02-20       Impact factor: 4.411

7.  Transfer hydrogenation of nitroarenes using cellulose filter paper-supported Pd/C by filtration as well as sealed methods.

Authors:  Dmitry Olegovich Bokov; Mustafa Z Mahmoud; Gunawan Widjaja; Wanich Suksatan; Supat Chupradit; Usama S Altimari; Hussein Ali Hussein; Yasser Fakri Mustafa; Milad Kazemnejadi
Journal:  RSC Adv       Date:  2022-04-07       Impact factor: 3.361

8.  Selective catalytic amination of halogenated aldehydes with calcined palladium catalysts.

Authors:  Alberto Villa; Kim Dumoleijn; Claudio Evangelisti; Kristof Moonen; Laura Prati
Journal:  RSC Adv       Date:  2018-04-23       Impact factor: 3.361

9.  Facile Hydrogenative Deprotection of N-Benzyl Groups Using a Mixed Catalyst of Palladium and Niobic Acid-on-Carbon.

Authors:  Yuta Yamamoto; Eisho Shimizu; Kazuho Ban; Yoshiyuki Wada; Tomoteru Mizusaki; Masatoshi Yoshimura; Yukio Takagi; Yoshinari Sawama; Hironao Sajiki
Journal:  ACS Omega       Date:  2020-02-05
  9 in total

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