| Literature DB >> 17997562 |
Al Postigo1, Sergey Kopsov, Carla Ferreri, Chryssostomos Chatgilialoglu.
Abstract
(Me3Si)3SiH was used as a successful reagent in a variety of radical-based transformations in water. The system comprising substrate, silane, and initiator (ACCN) mixed in aqueous medium at 100 degrees C worked well for both hydrophilic and hydrophobic substrates, with the only variation that an amphiphilic thiol was also needed in case of the water-soluble compounds.Entities:
Year: 2007 PMID： 17997562 DOI： 10.1021/ol7020803
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005