Literature DB >> 17997526

Ligands for practical rhodium-catalyzed asymmetric hydroformylation.

Jerzy Klosin1, Clark R Landis.   

Abstract

A series of bis-phosphite and bis-phosphine ligands for asymmetric hydroformylation reactions has been evaluated. Bis-phosphite ligands lead, in general, to high regioselectivities across a range of substrates while good enantioselectivities are limited to only a few examples. We found that bis-phospholane-type ligands, such as bis-diazaphospholanes and bis-phospholanes, can lead to very high regio- and enantioselectivities for several different substrates.

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Year:  2007        PMID： 17997526     DOI： 10.1021/ar7001039

Source DB:  PubMed          Journal:  Acc Chem Res        ISSN： 0001-4842            Impact factor:   22.384


  20 in total

1.  Stereochemically versatile synthesis of the C1-C12 fragment of tedanolide C.

Authors:  Thomas E Smith; Sarah J Fink; Zebulon G Levine; Kerani A McClelland; Adrian A Zackheim; Mary E Daub
Journal:  Org Lett       Date:  2012-02-29       Impact factor: 6.005

2.  Catalytic Enantioselective Hetero-dimerization of Acrylates and 1,3-Dienes.

Authors:  Stanley M Jing; Vagulejan Balasanthiran; Vinayak Pagar; Judith C Gallucci; T V RajanBabu
Journal:  J Am Chem Soc       Date:  2017-11-22       Impact factor: 15.419

3.  Synthesis of quaternary carbon centers via hydroformylation.

Authors:  X Sun; K Frimpong; K L Tan
Journal:  J Am Chem Soc       Date:  2010-09-01       Impact factor: 15.419

4.  The scope and mechanism of palladium-catalysed Markovnikov alkoxycarbonylation of alkenes.

Authors:  Haoquan Li; Kaiwu Dong; Haijun Jiao; Helfried Neumann; Ralf Jackstell; Matthias Beller
Journal:  Nat Chem       Date:  2016-09-05       Impact factor: 24.427

5.  Enantioselective Synthesis of 4-Methyl-3,4-dihydroisocoumarin via Asymmetric Hydroformylation of Styrene Derivatives.

Authors:  Bo Qu; Renchang Tan; Madison R Herling; Nizar Haddad; Nelu Grinberg; Marisa C Kozlowski; Xumu Zhang; Chris H Senanayake
Journal:  J Org Chem       Date:  2019-03-06       Impact factor: 4.354

6.  Tandem catalysis for asymmetric coupling of ethylene and enynes to functionalized cyclobutanes.

Authors:  Vinayak Vishnu Pagar; T V RajanBabu
Journal:  Science       Date:  2018-07-06       Impact factor: 47.728

7.  Application of a chiral scaffolding ligand in catalytic enantioselective hydroformylation.

Authors:  Amanda D Worthy; Candice L Joe; Thomas E Lightburn; Kian L Tan
Journal:  J Am Chem Soc       Date:  2010-10-27       Impact factor: 15.419

8.  Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands.

Authors:  Richard I McDonald; Gene W Wong; Ram P Neupane; Shannon S Stahl; Clark R Landis
Journal:  J Am Chem Soc       Date:  2010-10-13       Impact factor: 15.419

9.  α-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation.

Authors:  Josephine Eshon; Floriana Foarta; Clark R Landis; Jennifer M Schomaker
Journal:  J Org Chem       Date:  2018-08-17       Impact factor: 4.354

10.  Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers.

Authors:  Craig R Smith; Hwan Jung Lim; Aibin Zhang; T V Rajanbabu
Journal:  Synthesis (Stuttg)       Date:  2009-01-01       Impact factor: 3.157
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