| Literature DB >> 17995178 |
Randall D Kamien1, Andrea J Liu.
Abstract
We link the thermodynamics of colloidal suspensions to the statistics of regular and random packings. Random close packing has defied a rigorous definition yet, in three dimensions, there is near universal agreement on the volume fraction at which it occurs. We conjecture that the common value of phi{rcp} approximately 0.64 arises from a divergence in the rate at which accessible states disappear. We relate this rate to the equation of state for a hard-sphere fluid on a metastable, noncrystalline branch.Entities:
Year: 2007 PMID: 17995178 DOI: 10.1103/PhysRevLett.99.155501
Source DB: PubMed Journal: Phys Rev Lett ISSN: 0031-9007 Impact factor: 9.161