Literature DB >> 17989835

Fast, efficient Ru(IV)-catalysed regioselective allylation of indoles using allyl alcohol (without additives) under mild conditions.

Alexey B Zaitsev1, Stefan Gruber, Paul S Pregosin.   

Abstract

The new Ru(IV) salt, [Ru(eta(3)-C(3)H(5))(Cp*)(CH(3)CN)(2)](PF(6))(2), is an excellent catalyst for the regioselective allylation of a variety of indole compounds using allyl alcohol as substrate; there are no co-catalysts required in this chemistry and the yields and reaction conditions are very favorable.

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Year:  2007        PMID： 17989835     DOI： 10.1039/b710763c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Friedel-Crafts Alkylation of Indoles with Trichloroacetimidates.

Authors:  Tamie Suzuki; John D Chisholm
Journal:  Tetrahedron Lett       Date:  2019-04-03       Impact factor: 2.415

2.  Palladium-catalyzed decarboxylative allylation and benzylation of N-alloc and N-Cbz indoles.

Authors:  Thomas D Montgomery; Ye Zhu; Natsuko Kagawa; Viresh H Rawal
Journal:  Org Lett       Date:  2013-02-21       Impact factor: 6.005

3.  A review of new developments in the Friedel-Crafts alkylation - From green chemistry to asymmetric catalysis.

Authors:  Magnus Rueping; Boris J Nachtsheim
Journal:  Beilstein J Org Chem       Date:  2010-01-20       Impact factor: 2.883

4.  Palladium-catalyzed beta-allylation of 2,3-disubstituted indoles.

Authors:  Natsuko Kagawa; Jeremiah P Malerich; Viresh H Rawal
Journal:  Org Lett       Date:  2008-05-21       Impact factor: 6.005

5.  Catalytic vinylogous cross-coupling reactions of rhenium vinylcarbenoids.

Authors:  Ji Chen; Jimmy Wu
Journal:  Chem Sci       Date:  2018-01-30       Impact factor: 9.825

6.  Rapid access to spirocyclized indolenines via palladium-catalyzed cascade reactions of tryptamine derivatives and propargyl carbonate.

Authors:  Thomas D Montgomery; Antoinette E Nibbs; Ye Zhu; Viresh H Rawal
Journal:  Org Lett       Date:  2014-06-25       Impact factor: 6.005
  6 in total

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