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Literature DB >> 17989812

A highly efficient non-heme manganese complex in oxygenation reactions.

Kasi Nehru¹, Soo Jeong Kim, In Young Kim, Mi Sook Seo, Youngmee Kim, Sung-Jin Kim, Jinheung Kim, Wonwoo Nam.

Abstract

A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.

Entities: Chemical

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Year: 2007 PMID： 17989812 DOI： 10.1039/b708976g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate.

Authors: Keigo Kamata; Kazuhiro Yonehara; Yoshinao Nakagawa; Kazuhiro Uehara; Noritaka Mizuno
Journal: Nat Chem Date: 2010-05-02 Impact factor: 24.427

2. Facile Routes to Manganese(II) Triflate Complexes.

Authors: Paul J Riedel; Navamoney Arulsamy; Mark P Mehn
Journal: Inorg Chem Commun Date: 2011-05 Impact factor: 2.495

3. Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes.

Authors: Elisa Tordin; Manuela List; Uwe Monkowius; Siegfried Schindler; Günther Knör
Journal: Inorganica Chim Acta Date: 2013-06-01 Impact factor: 2.545

A highly efficient non-heme manganese complex in oxygenation reactions.

1. Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate.

2. Facile Routes to Manganese(II) Triflate Complexes.

3. Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes.

4. Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide.

5. cis-Oxoruthenium complexes supported by chiral tetradentate amine (N₄) ligands for hydrocarbon oxidations.

6. Aerobic alcohol oxidation and oxygen atom transfer reactions catalyzed by a nonheme iron(ii)-α-keto acid complex.

A highly efficient non-heme manganese complex in oxygenation reactions.

1. Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate.

2. Facile Routes to Manganese(II) Triflate Complexes.

3. Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes.

4. Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide.

5. cis-Oxoruthenium complexes supported by chiral tetradentate amine (N4) ligands for hydrocarbon oxidations.

6. Aerobic alcohol oxidation and oxygen atom transfer reactions catalyzed by a nonheme iron(ii)-α-keto acid complex.

5. cis-Oxoruthenium complexes supported by chiral tetradentate amine (N₄) ligands for hydrocarbon oxidations.