Literature DB >> 17989459

(2,2'-Biquinoline-kappa2N,N')bis(nitrato-kappa2O,O')copper(II).

Yanko Moreno1, Yimmy Salgado, María Teresa Garland, Ricardo Baggio.   

Abstract

In the title monomer, [Cu(NO(3))(2)(C(18)H(12)N(2))], the six-coordinated Cu(II) atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

Entities:  

Year:  2007        PMID: 17989459     DOI: 10.1107/S0108270107046513

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  The cocrystal μ-oxalato-κO,O:O,O-bis-(aqua-(nitrato-κO){[1-(2-pyridyl-κN)eth-ylidene]hydrazine-κN}copper(II)) μ-oxalato-κO,O:O,O-bis-((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)eth-ylidene]hydrazine-κN}copper(II)) (1/1).

Authors:  Madina Diallo; Farba Bouyagui Tamboura; Mohamed Gaye; Aliou Hamady Barry; Youssouph Bah
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-08-06

2.  (2,2'-Biquinoline-κN,N')dibromido-zinc(II).

Authors:  Hamideh Saravani; Ali Reza Rezvani; Niloufar Akbarzadeh Torbati
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-24
  2 in total

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