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Literature DB >> 17983220

Synthesis and characterization of an iron(II) eta(2)-hydrazine complex.

Justin L Crossland¹, Lev N Zakharov, David R Tyler.

Abstract

The iron phosphine complex cis-[Fe(DMeOPrPE)2(eta2-N2H4)][BPh4]2 {DMeOPrPE = 1,2-bis[bis(methoxypropyl)phosphino]ethane} was synthesized and structurally characterized. The structure exhibits the first eta2 coordination of hydrazine to iron, which may be relevant to intermediates trapped during nitrogenase turnover. The reaction of I with acid results in the formation of ammonia via a disproportionation reaction.

Entities: Chemical Gene

Mesh：

Substances：
Hydrazines
hydrazine
Iron

Year: 2007 PMID： 17983220 DOI： 10.1021/ic702007r

Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165

Keyword Cloud
Cited

8 in total

Review 1. Catalytic N₂-to-NH₃ (or -N₂H₄) Conversion by Well-Defined Molecular Coordination Complexes.

Authors: Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal: Chem Rev Date: 2020-04-30 Impact factor: 60.622

2. A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.

Authors: Caroline T Saouma; Curtis E Moore; Arnold L Rheingold; Jonas C Peters
Journal: Inorg Chem Date: 2011-10-17 Impact factor: 5.165

3. A Sulfide-Bridged Diiron(II) Complex with a cis-N₂H₄Ligand.

Authors: Bryan D Stubbert; Javier Vela; William W Brennessel; Patrick L Holland
Journal: Z Anorg Allg Chem Date: 2013-07-01 Impact factor: 1.492

4. Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives.

Authors: S Chantal E Stieber; Carsten Milsmann; Jordan M Hoyt; Zoë R Turner; Kenneth D Finkelstein; Karl Wieghardt; Serena Debeer; Paul J Chirik
Journal: Organometallics Date: 2012-03-12 Impact factor: 3.876

5. Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

Authors: Yunho Lee; Neal P Mankad; Jonas C Peters
Journal: Nat Chem Date: 2010-05-16 Impact factor: 24.427

Synthesis and characterization of an iron(II) eta(2)-hydrazine complex.

Review 1. Catalytic N₂-to-NH₃ (or -N₂H₄) Conversion by Well-Defined Molecular Coordination Complexes.

2. A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.

3. A Sulfide-Bridged Diiron(II) Complex with a cis-N₂H₄Ligand.

4. Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives.

5. Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

6. (Ethane-1,2-di-yl)bis-[bis-(3-methoxy-prop-yl)methyl-phospho-nium] bis-(tetra-phenyl-borate) diethyl ether solvate.

7. Mononuclear five- and six-coordinate iron hydrazido and hydrazine species.

8. Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic.

Review 1. Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Review 1. Catalytic N₂-to-NH₃ (or -N₂H₄) Conversion by Well-Defined Molecular Coordination Complexes.