Literature DB >> 17975928

Oppenauer oxidation of secondary alcohols with 1,1,1-trifluoroacetone as hydride acceptor.

Rossella Mello1, Jaime Martínez-Ferrer, Gregorio Asensio, María Elena Gonzalez-Núñez.   

Abstract

1,1,1-Trifluoroacetone (2a) reacts as a hydride-acceptor in the Oppenauer oxidation of secondary alcohols (1) in the presence of diethylethoxyaluminum. The oxidant allows for selective oxidation of secondary alcohols in the presence of primary alcohols.

Entities:  

Year:  2007        PMID： 17975928     DOI： 10.1021/jo7016422

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  On the synergistic catalytic properties of bimetallic mesoporous materials containing aluminum and zirconium: the Prins cyclisation of citronellal.

Authors:  Selvedin Telalović; Anand Ramanathan; Jeck Fei Ng; Rajamanickam Maheswari; Cees Kwakernaak; Fouad Soulimani; Hans C Brouwer; Gaik Khuan Chuah; Bert M Weckhuysen; Ulf Hanefeld
Journal:  Chemistry       Date:  2011-01-21       Impact factor: 5.236

2.  Dual utility of a single diphosphine-ruthenium complex: a precursor for new complexes and, a pre-catalyst for transfer-hydrogenation and Oppenauer oxidation.

Authors:  Aparajita Mukherjee; Samaresh Bhattacharya
Journal:  RSC Adv       Date:  2021-04-27       Impact factor: 3.361
  2 in total

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