Literature DB >> 17960081

Aqueous Ti(IV)-catalyzed Diels-Alder reaction.

Kyle E Litz1.   

Abstract

The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P, a novel Ti(IV) performance catalyst. The catalyst improved conversion by 22% versus the uncatalyzed reaction and represents a rare example of a Ti(IV) catalyzed Diels-Alder reaction in water.

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Year:  2007        PMID： 17960081      PMCID： PMC6149148          DOI： 10.3390/12081674

Source DB:  PubMed          Journal:  Molecules        ISSN： 1420-3049            Impact factor:   4.411


  3 in total

1.  Stereoselective organic reactions in water.

Authors:  Ulf M Lindström
Journal:  Chem Rev       Date:  2002-08       Impact factor: 60.622

2.  Efficient catalysis of a Diels-Alder reaction by metallo-vesicles in aqueous solution.

Authors:  T Rispens; J B Engberts
Journal:  Org Lett       Date:  2001-03-22       Impact factor: 6.005

3.  Substrate dependence in aqueous Diels-Alder reactions of cyclohexadiene derivatives with 1,4-benzoquinone.

Authors:  Takeshi Sunakawa; Chiaki Kuroda
Journal:  Molecules       Date:  2005-01-31       Impact factor: 4.411
  3 in total

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