Literature DB >> 17957297

Organocatalysts wrapped around by poly(ethylene glycol)s (PEGs): a unique host-guest system for asymmetric Michael addition reactions.

Dan Qian Xu1, Shu Ping Luo, Yi Feng Wang, Ai Bao Xia, Hua Dong Yue, Li Ping Wang, Zhen Yuan Xu.   

Abstract

Asymmetric Michael addition reactions of unmodified ketones to nitroalkenes were performed in PEGs catalyzed by novel pyrrolidinyl-thioimidazolium salts to give products in up to 97% yield and 99% enantioselectivity; ESI mass spectrometric detection for the first time gave evidence of the presence of the PEG-organocatalyst host-guest complex.

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Year:  2007        PMID: 17957297     DOI: 10.1039/b708525g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  (1S,4S,5S,6R)-6-(4-Bromo-phen-yl)-5-nitro-bicyclo-[2.2.2]octan-2-one.

Authors:  Aibao Xia; Jie Tang; Yifeng Wang; Junrong Jiang; Shuping Luo
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-01-17

2.  (S)-2-(Pyrrolidinium-2-ylmethyl-sulfan-yl)pyridinium dibromide.

Authors:  Shuai Zhang; Yifeng Wang; Aibao Xia; Shuping Luo
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-05-24

3.  trans-2-(2-Nitro-1-phenyl-eth-yl)cyclo-hexa-none.

Authors:  Ivo Zenz; Herbert Mayr; Peter Mayer
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-13
  3 in total

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